Papers

BAND-GAP ENGINEERING IN A NEW FAMILY OF HETEROMETALLIC TITANIUM(IV) METAL-ORGANIC FRAMEWORKS


Javier Castells & Natalia M. Padial’s work has just been published as a Very Important Paper in Angewandte Chemie Int. Ed. The work describes a new family of heterometallic Titanium(IV)-based Metal Organic Frameworks, namely MUV-10, that can be produced in gram quantity and show remarkable stability in water. Moreover, the paper shows how the electronic structure of these materials can be tuned through the heterometallic centres by means of metal doping, which is further supported by theoretical calculations and by photocatalytic H2 production from water, in collaboration with Hermenegildo García’s group at ITQ. For more info see here.

BAND-GAP ENGINEERING IN A NEW FAMILY OF HETEROMETALLIC TITANIUM(IV) METAL-ORGANIC FRAMEWORKS


José Navarro’s work to be featured in the “New Talents: Europe” special issue in Dalton Transactions investigates the structural response of a dense peptide metal–organic framework of Zn(GlyTyr)2. This material shows a reversible compression by 13% in volume at 4 GPa that is facilitated by the ability of the peptidic linker to fold cooperatively. Compared to other structural transformations in Zn(II) peptide MOFs, this behaviour is not affected by host/guest interactions and relies exclusively on the conformational flexibility of the peptide and its side chain chemistry. For more info see here.

DEVICE FABRICATION OF ELECTRICALLY CONDUCTIVE ULTRATHIN FILMS OF A TWO-DIMENSIONAL MOF


Víctor Rubio’s work has just been accepted in Advanced Materials. This paper reports on the convenience of a solution-based bottom-up method, which combines the use of the Langmuir-Blodgett technique, Layer-by-Layer and self-assembled monolayers to transfer high-quality ultrathin films of a semiconductive 2D MOF in a controlled fashion. This versatile methodology enabled us to fabricate MOF-based electronic devices and study the electrical conductivity on the thinnest MOF films (10 nm thick) reported so far. For more info see here.

FUNCTIONALIZATION OF MOF CRYSTALS WITH CATECHOL COATINGS FOR ENHANCED MOISTURE TOLERANCE.


Javier Castell’s paper in ACS Applied Materials & Interfaces demonstrates the formation of robust catechol coatings for enhanced moisture tolerance by one step reaction of HKUST crystals with synthetic catechols. In collaboration with D. Ruiz-Molinas’ grout @ICN2 we show that the use of fluorinated catechols results in hydrophobic, permeable coatings that protect HKUST from water degradation whilst retaining close to 100 % of its original sorption capacity. For more info see here.

METAL DOPING FOR SPONTANEOUS MAGNETIZATION IN MICROPOROUS MAGNETS


Víctor Rubio’s Chem. Mater. paper reports on the controllable doping of Ni-MOF-74 with Fe to produce a MOF material which combines porosity and ferrimagnetic ordering. This validates metal doping as a useful strategy to modify the magnetism of other archetypical families of MOFs. For more info see here.

JACS paper on peptide MOFs for enantioselective separation of chiral drugs.


José Navarro’s work has just been published in JACS. In collaboration with the MINOLTA team at UVEG we report the first example of a MOF capable of separating chiral polar drugs. Cu- GlyHisGly is capable of separating more than 50% of the (+)-ephedrine enantiomer from a racemic mixture in only.

bioMOFs

bioMOFs for mercury removal published in Angewandte Chemie.


In collaboration with E. Pardo’s group at ICMol, this work highlights the potential of flexible MOFs incorporating amino acids to enable efficient removal of mercury from solution. This porous solid displays an adaptable response reminiscent of that responsible for the biological activity of the enzyme mercuric reductase.

Electroactive MOF

Electroactive MOF thin-films in JACS


Victor Rubio’s JACS paper reports on the use of self-assembled monolayers (SAMs) to enable the fabrication of highly oriented, ultrathin MOF films across millimetre-scale areas. Electrical conductivity was studied with Hg-drop electrometry. This strategy might be useful for the integration of MOFs as active interfaces in electronic devices.

Group news

JUSTINE CORDIEZ JOINS THE TEAM


Justine is originally from Lille, France. She joins the team as a visiting Erasmus Student. Her research will focus on controlling defects in the family of titanium MOFs MUV-10.

SERGIO TATAY JOINS FUNIMAT


Sergio is Valencian born and breed. He earned his Ph.D. in 2008, working in the group of Prof. Eugenio Coronado at the Universidad de Valencia. She next joined the Unité Mixte of Physicque CNRS/THALES. He received a Ramón y Cajal Fellowship in 2017 and will be leading the development of electronic devices based on conductive MOFs @Funimat.

Neyvis Almora

NEYVIS ALMORA JOINS THE TEAM


Neyvis Almora-Barrios is original from La Havana, Cuba, and earned her Ph.D. in 2010, working in the group of Prof. Nora de Leeuw at the University College of London, UK. She next joined Prof. Nuria López’s group at the Institute of Chemical Research of Catalonia (ICIQ). She will be in charge of computational modelling to study structure-properties relationships in the porous materials developed @Funimat

CAROLINA RUIZ-GANIVET


Carolina Ruiz-Ganivet is original of Madrid and earned her Ph.D. in 2015, working in the group of Prof. Tomás Torres at the Universidad Autónoma de Madrid. She next joined Prof. Luis Echegoyen’s group at the University of Texas at el Paso (USA). She will responsible for most of the organic aspects of the synthesis of the MOFs developed @Funimat.

BELÉN LERMA STARTS HER PhD

BELÉN LERMA STARTS HER PhD


Belen is Valencia born and bred. She earned a degree (2016) and Master (2017) in Chemistry at the Universidad de Valencia and now joins the team as PhD Student. Her research will focus on the development of high-throughput methodologies for the synthesis of biomimetic MOFs that feature high-stability and increasing pore complexity.

Natalia Muñoz

Natalia Muñoz joins us


Natalia is originally from Granada and completed her PhD in the Universidad of Granada in 2016 under the supervision of Jorge A. Rodriguez Navarro and Enrique Oltra. She will be working on the synthesis of non-conventional MOF-forming linkers.

Gokhan Gureser

Gokhan Gureser joins the team


Gokhan is originally from Turkey and completed his BSc. In Chemical Engineering from the University of Bogazici in 2005. He enrols the team as a Master Student and will be working on the nanostructuration of layered MOFs on solid substrates.

Alejandro Núnez

Alejandro Nuñez joins the team


Alejandro is Valencia born and bred. He earned a degree in Chemistry from the Universidad de Valencia in 2016 and joins the team as a Master Student. His research will focus on the development of MOFs that feature high-stability and photoactivity.

MARIA ROMERO IS OUR NEW MASTER STUDENT


Maria graduated in Chemical Engineering in 2015 at the University of Valencia and worked with an internship at the plastic technology institute, AIMPLAS. She joins the team as a Master Student. Her research will focus on controlling mass transport and reactivity in stable MOFs by defect engineering.

General info

ROSS FORGAN VISITS US FOR AN INVITED LECTURE


Ross Forgan, URF and Chemistry Reader at the University of Glasgow, visited us to lecture on the research of his team on the development of new applications based on zirconium (IV) metal-organic frameworks. We are hopeful this will initiate a fruitful collaboration between both groups.

ELENA LOPEZ AWARDED A JdC FELLOWSHIP


Elena Lopez Maya, currently a Postdoctoral Researcher at the University of Versailles in France, has received a Juan de la Cierva in the category Formación to join FuniMat by the end of the year. Congratulations!

EMILIO COCINERO VISITS US FOR AN INVITED LECTURE


Emilio J. Cocinero leader of the Spectroscopy Group at the UPV/EHU visited us to present their research on how high-resolution spectroscopy in the microwave region can be used to solve problems in modern chemistry.

INVITED SEMINAR AT THE UAB


Carlos visited the Universidad Autónoma de Barcelona for an invited seminar to present our research on flexible peptide-MOFs for chiral drugs separation and high-pressure structural transformations.

FUNIMAT AT ACS NOLA AND docMOF


Funimat was present at the ACS Symposium held in New Orleans and the docMOF symposium held in Germany. Carlos delivered a talk on charge transport in MOF ultrathin films and Javi presented our recent work in Titanium MOFs.

INVITED SEMINARS AT THE UPV/EHU & IMPERIAL COLLEGE


Carlos visited the UPV/EHU in Bilbao and the Imperial College of London for two invited seminars to present our recent advances in charge transport and photo-activity in metal-organic frameworks.

ROB AMELOOT VISITS US FOR AN INVITED LECTURE


Rob Ameloot from KU Leuven visited us to lecture on the research of his team on chemical vapor deposition of metal-organic frameworks. We are hopeful this will initiate a fruitful collaboration between both groups.

INVITED SEMINAR AT THE UAM


Carlos visited the Universidad Autónoma de Madrid for an invited seminar to present our research on the sidechain engineering of porosity and structural flexibility of peptide metal-organic frameworks.

MINECO PROJECT GRANTED


We have been awarded a 3 years project financed by MINECO that also includes a PhD Scholarship to develop Metal-Organic Frameworks of Biological Inspiration (CTQ2017-83486-P).

LECTURE AT EUROMOF17


Funimat was present at the 2nd European Conference in Metal-Organic Frameworks held in Delft. Carlos delivered a talk on ‘Peptide MOFs for enantioselective separation of chiral drugs’ and Javi & Natalia presented posters featuring our most recent work.

KEYNOTE LECTURE AT INTERNATIONAL SYMPOSIUM ON MOFs AND COFs

KEYNOTE LECTURE AT INTERNATIONAL SYMPOSIUM ON MOFs AND COFs


Funimat was present at the International Symposium on Composites of Metal and Covalent Organic Frameworks held in Granada. Carlos delivered a keynote lecture on ‘Charge Transport in Ultrathin films of Metal-Organic Framewors’. For more details see here.

INVITED LECTURE AT ECMM17

INVITED LECTURE AT ECMM17


Funimat was present at the 6th European Conference in Molecular Magnetism held in Bucharest. Carlos delivered an invited talk on ‘Ultrathin films of layered coordination polymers: charge transport and spin-crossover at the nanoscale’. For more details see here.

NATALIA AND BELEN WIN COMPETITIVE FUNDING

NATALIA AND BELEN WIN COMPETITIVE FUNDING


Natalia and Belen have recently been awarded a Juan de La Cierva Formación Fellowship and FPU Scholarship, respectively. These are quite competitive calls funded by the Spanish MINECO that highlight their excellent scientific and academic performance. Congratulations!

KEYNOTE LECTURE AT RSEQ BIENAL

KEYNOTE LECTURE AT RSEQ BIENAL


Funimat was present at the XXXVI Bienal de la Real Sociedad Española de Química held in Sitges. Carlos and Victor delivered keynote and flash presentations at the MOF symposium highlighting most recent results of the team in ‘Peptide-based porous materials’ and ‘Conductive ultrathin MOF films’. For more details see here.

ERC

ERC Stg Grant Chem-fs-MOF awarded


The European Research Council has awarded an ERC Starting Grant to Carlos. The money will be used to develop advanced porous materials for their implementation in applications of environmental relevance like solar energy conversion or the development of a new generation of electronic devices that combine porosity and electrical response.

Metal Composite

Our work featured in the Emerging Investigators Issue


Our work on MOFs for supercapacitors has been highlighted in the Chem. Commun. Emerging Investigators Issue. This special issue, now in its sixth year, intends to showcase the high-quality research being carried out by international researchers in the early stages of their independent careers